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3.10.2013 Official
Journal
of
the
European
Union L
261/5
COMMISSION REGULATION (EU) No 944/2013
of 2 October 2013
amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No
1272/2008 of the European Parliament and of the Council on classification, labelling and packaging
of substances and mixtures
(Text with EEA relevance)
THE EUROPEAN COMMISSION,
labelling of substances which had been submitted to
ECHA pursuant to Article 37 of Regulation (EC) No
1272/2008. Based on those opinions, as well as on the
Having regard to the Treaty on the Functioning of the European
comments received from the parties concerned, it is
Union,
appropriate to amend Annex VI to Regulation (EC) No
1272/2008 in order to harmonise the classification and
labelling of certain substances.
Having regard to Regulation (EC) No 1272/2008 of the
European Parliament and of the Council of 16 December
2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC
(4) The
harmonised
classifications
set
out
in
Part
3
of
Annex
and 1999/45/EC, and amending Regulation (EC) No
VI to Regulation (EC) No 1272/2008, as amended by this
1907/2006 (
Regulation, should not apply immediately, as a certain

1 ), and in particular Article 37(5) and Article 53
thereof,
period of time will be necessary to allow operators to
adapt the labelling and packaging of substances and
mixtures to the new classifications and to sell existing
stocks. In addition, a certain period of time will be
Whereas:
necessary to allow operators to comply with the regis
tration obligations resulting from the new harmonised
classifications for substances classified as carcinogenic,
(1) In
respect
of
precautionary
statement
P210
set
out
in
mutagenic or toxic to reproduction, categories 1A and
table 6.2 Part 1 of Annex IV to Regulation (EC) No
1B (Table 3.1) and categories 1 and 2 (Table 3.2), or as
1272/2008 the 5th revision of the Globally Harmonised
very toxic to aquatic organisms which may cause long
System of Classification and Labelling of Chemicals (here
term effects in the aquatic environment, in particular
inafter ‘GHS’) of the United Nations has brought about
with those set out in Article 23 of Regulation (EC) No
changes which were not fully taken into account in
1907/2006 of the European Parliament and of the
Commission Regulation (EU) No 487/2013 ( 2 ). For
Council of 18 December 2006 concerning the Regis
reasons of consistency it is necessary to provide for full
tration, Evaluation, Authorisation and Restriction of
alignment between the GHS and Regulation (EC) No
Chemicals (REACH), establishing a European Chemicals
1272/2008.
Agency, amending Directive 1999/45/EC and repealing
Council Regulation (EEC) No 793/93 and Commission
Regulation (EC) No 1488/94 as well as Council
(2) Part
3
of
Annex
VI
to
Regulation
(EC)
No
1272/2008
Directive 76/769/EEC and Commission Directives
contains two lists of harmonised classification and
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC ( 4 ).
labelling of hazardous substances. Table 3.1 lists the
harmonised classification and labelling of hazardous
substances based on the criteria set out in Parts 2 to 5
of Annex I to Regulation (EC) No 1272/2008. Table 3.2
(5) With
regard
to
the
substance
pitch,
coal
tar,
high-temp.
lists the harmonised classification and labelling of
(EC Number: 266-028-2), an extended period of time
hazardous substances based on the criteria set out in
will be necessary to allow operators to comply with
Annex VI to Council Directive 67/548/EEC of 27 June
the obligations resulting from the new harmonised clas
1967 on the approximation of laws, regulations and
sification for substances classified as very toxic to aquatic
administrative provisions relating to the classification,
organisms which may cause long term effects in the
packaging and labelling of dangerous substances ( 3 ).
aquatic environment, in particular with those set out in
Those two lists need to be amended to include updated
Article 3 and Annex III of Directive 2008/68/EC of the
classifications for substances already subject to those
European Parliament and of the Council of 24 September
harmonised classifications and to include new
2008 on the inland transport of dangerous goods ( 5 ).
harmonised classifications.
Therefore, a longer transition time should be foreseen
before the harmonised classification has to be applied.
(3) The
Committee
for
Risk
Assessment
(RAC)
of
the
European Chemicals Agency (ECHA) has issued
opinions on proposals for harmonised classification and
(6) With
regard
to
the
substance
gallium
arsenide
(EC
Number: 215-114-8), the RAC is in the process of
( 1 ) OJ L 353, 31.12.2008, p. 1.
( 2 ) OJ L 149, 1.6.2013, p. 1.
( 4 ) OJ L 396, 30.12.2006, p. 1.
( 3 ) OJ 196, 16.8.1967, p. 1.
( 5 ) OJ L 260, 30.9.2008, p. 13.

---

L 261/6
EN
Official Journal of the European Union
3.10.2013
adopting a new opinion for the hazard class ‘toxicity to
(ii) The entries set out in Annex III to this Regulation
reproduction’. Therefore, this hazard class should not be
are inserted in accordance with the order of the
included in Annex VI to Regulation (EC) No 1272/2008
entries set out in Table 3.1.
until that opinion is finalised.
(b) Table 3.2 is amended as follows:
(7) With
regard
to
the
substance
polyhexamethylene
biguanide hydrochloride (CAS number 27083-27-8 or
32289-58-0), new scientific data has been made
(i) The entries set out in Annex VI to Regulation (EC)
available for the hazard class ‘acute toxicity (inhalation)’,
No 1272/2008 corresponding to the entries set out
which suggests that the classification for this hazard class
in Annex IV to this Regulation are replaced by the
as recommended in the RAC opinion, which is based on
entries set out in in Annex IV to this Regulation;
older data, might not be appropriate. Therefore, this
hazard class should not be included in Annex VI to
Regulation (EC) No 1272/2008 until RAC has had the
opportunity to deliver an opinion on the new
(ii) The entries set out in Annex V to this Regulation
information, while all other hazard classes covered by
are inserted in accordance with the order of the
the earlier RAC opinion should be included.
entries set out in Table 3.2.
Article 2
(8) In
line
with
the
transitional
provisions
of
Regulation
(EC)
No 1272/2008 which allow the application of the new
1. By
way
of
derogation
from
Article
3(2)
substances
and
provisions at an earlier stage on a voluntary basis,
mixtures may, before 1 December 2014 and 1 June 2015
suppliers should have the possibility of applying the
respectively, be classified, labelled and packaged in accordance
harmonised classifications set out in Part 3 of Annex
with Regulation (EC) No 1272/2008 as amended by this Regu
VI to Regulation (EC) No 1272/2008, as amended by
lation.
this Regulation, and of adapting the labelling and
packaging accordingly on a voluntary basis before the
dates by which the harmonised classifications will
2. By
way
of
derogation
from
Article
3(2),
substances
clas
become mandatory.
sified, labelled and packaged in accordance with Regulation (EC)
No 1272/2008 and placed on the market before 1 December
2014, shall not be required to be relabelled and repackaged in
(9) The
measures
provided
for
in
this
Regulation
are
in accordance with Regulation (EC) No 1272/2008 as amended by
accordance with the opinion of the Committee estab
this Regulation until 1 December 2016.
lished under Article 133 of Regulation (EC) No
1907/2006,
3. By
way
of
derogation
from
Article
3(2)
mixtures
classified,
labelled and packaged in accordance with Directive 1999/45/EC
of the European Parliament and of the Council ( 1 ) or Regulation
HAS ADOPTED THIS REGULATION:
(EC) No 1272/2008 and placed on the market before 1 June
2015, shall not be required to be relabelled and repackaged in
accordance with Regulation (EC) No 1272/2008 as amended by
Article 1
this Regulation until 1 June 2017.
Regulation (EC) No 1272/2008 is amended as follows:
4. By
way
of
derogation
from
Article
3(3)
the
harmonised
classifications set out in Part 3 of Annex VI to Regulation (EC)
(1) Annex IV is amended in accordance with the Annex I to
No 1272/2008, as amended by this Regulation, may be applied
this Regulation;
before the dates referred to in Article 3(3).
Article 3
(2) Part 3 of Annex VI is amended as follows:
1. This
Regulation
shall
enter
into
force
on
the
twentieth
day
following that of its publication in the Official Journal of the
European Union.
(a) Table 3.1 is amended as follows:
2. Article
1(1)
shall
apply
in
respect
of
substances
from
(i) The entries set out in Annex VI to Regulation (EC)
1 December 2014 and in respect of mixtures from 1 June
No 1272/2008 corresponding to the entries set out
2015.
in Annex II to this Regulation are replaced by the
entries set out in Annex II to this Regulation;
( 1 ) OJ L 200, 30.7.1999, p. 1.

---

EN
3.10.2013 Official
Journal
of
the
European
Union L
261/7
3. Article 1(2) shall apply from 1 January 2015 for all entries except for the entry pitch, coal tar, high-
temp. (EC Number 266-028-2), for which Article 1 shall apply from 1 April 2016.
This Regulation shall be binding in its entirety and directly applicable in all Member States.
Done at Brussels, 2 October 2013.
For the Commission
The President
José Manuel BARROSO

---

L 261/8
EN
Official Journal of the European Union
3.10.2013
ANNEX I
In Part 1, Table 6.2 of Annex IV to Regulation (EC) No 1272/2008, Code P210 is replaced by the following:
‘P210 Keep
away
from
heat,
hot Explosives (section 2.1) Divisions
1.1,
surfaces, sparks, open flames
1.2, 1.3, 1.4,
and other ignition sources.
1.5
No smoking.
Flammable gases (section 2.2) 1,
2
Aerosols (section 2.3) 1,
2,
3
Flammable liquids (section
1, 2, 3
2.6)
Flammable solids (section 2.7) 1,
2
Self-reactive substances and Types A, B, C,
mixtures (section 2.8)
D, E, F
Pyrophoric liquids (section
1
2.9)
Pyrophoric solids (section
1
2.10)
Oxidising liquids (section
1, 2, 3
2.13)
Oxidising solids (section 2.14) 1,
2,
3
Organic peroxides (section Types A, B, C,
2.15)
D, E, F’

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3.10.2013 Off
ANNEX II
Classification Labelling
Index No International
Chemical
Identification EC
No CAS
No
Suppl.
Specific Conc. Limits,
Hazard statement
Pictogram,
Hazard statement
Hazard
M — Factors
Notes
Hazard Class and
Category Code(s)
Code(s)
Signal Word
Code(s)
Code(s)
statement
EN
Code(s)

015-004-00-8 aluminium
phosphide 244-088-0 20859-73-8 Water-react.
1 H260 GHS02 H260 EUH029 M
=
100
Acute Tox. 2 H300 GHS06 H300 EUH032
Acute Tox. 3 H311 GHS09 H311
Acute Tox. 1 H330 Dgr H330
Aquatic Acute 1 H400 H400
015-005-00-3 magnesium
phosphide;
235-023-7 12057-74-8 Water-react.
1 H260 GHS02 H260 EUH029 M
=
100
trimagnesium diphosphide
Acute Tox. 2 H300 GHS06 H300 EUH032
icial
Acute Tox. 3 H311 GHS09 H311
Jour
Acute Tox. 1 H330 Dgr H330
Aquatic Acute 1 H400 H400
nal
of
the
015-123-00-5 fenamiphos
(ISO);
244-848-1 22224-92-6 Acute
Tox.
2 H300 GHS06 H300 M
=
100
European
ethyl-4-methylthio-m-tolyl isopropyl
M = 100
Acute Tox. 2 H310 GHS09 H310
phosphoramidate
Acute Tox. 2 H330 Dgr H330
Eye Irrit. 2 H319 H319
Union
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410
030-012-00-1 aluminium-magnesium-zinc-carbonate- 423-570-6 169314-88-9 Aquatic
Chronic
4 H413 H413
hydroxide
602-006-00-4 chloroform;
200-663-8 67-66-3 Carc.
2 H351 GHS06 H351
trichloromethane
Repr. 2 H361d GHS08 H361d
Acute Tox. 3 H331 Dgr H331
Acute Tox. 4 H302 H302
STOT RE 1 H372 H372
Eye Irrit. 2 H319 H319
Skin Irrit. 2 H315 H315
L
603-097-00-3 1,1’,1’-nitrilotripropan-2-ol;
204-528-4 122-20-3 Eye
Irrit.
2 H319 GHS07
H319
261/9
triisopropanolamine
Wng

---

L 261/10
Classification Labelling
Index No International
Chemical
Identification EC
No CAS
No
Suppl.
Specific Conc. Limits,
Hazard statement
Pictogram,
Hazard statement
Hazard
M — Factors
Notes
Hazard Class and
Category Code(s)
Code(s)
Signal Word
Code(s)
Code(s)
statement
Code(s)
605-008-00-3 acrolein;
203-453-4 107-02-8 Flam.
Liq.
2 H225 GHS02 H225 EUH071 Skin
Corr.
1;
D
EN
prop-2-enal;
Acute Tox. 1 H330 GHS06 H330
H314: C ≥ 0,1 %

acrylaldehyde
Acute Tox. 2 H300 GHS05 H300
Acute Tox. 3 H311 GHS09 H311
Skin Corr. 1 H314 Dgr H314
Aquatic Acute 1 H400 M
=
100
Aquatic Chronic 1 H410 H410 M
=
1
607-023-00-0 vinyl
acetate 203-545-4 108-05-4 Flam.
Liq.
2 H225 GHS02 H225
D
Carc. 2 H351 GHS08 H351
Off
Acute Tox. 4 H332 GHS07 H332
STOT SE 3 H335 Dgr H335
icial
Jour
607-613-00-8 reaction
mass
of:
432-790-1 Acute
Tox.
4* H332 GHS07 H332
nal
succinic acid
Acute Tox. 4* H312 GHS05 H312
monopersuccinic acid
of
Acute Tox. 4* H302 GHS08 H302
dipersuccinic acid
the
Skin Corr. 1B H314 Dgr H314
monomethyl ester of succinic acid
STOT SE 2 H371
(eyes) H371
(eyes)
European
monomethyl ester of persuccinic acid
dimethyl succinate glutaric acid
monoperglutaric acid
diperglutaric acid
Union
monomethyl ester of glutaric acid
monomethyl ester of perglutaric acid
dimethyl glutarate adipic acid
monoperadipic acid
diperadipic acid
monomethyl ester of adipic acid
monomethyl ester of peradipic acid
dimethyl adipate
hydrogen peroxide
methanol
water
609-003-00-7 nitrobenzene 202-716-0 98-95-3 Carc.
2. H351 GHS06 H351
Repr. 1B H360F GHS08 H360F
Acute Tox. 3 H301 Dgr H301
Acute Tox. 3 H331 H331
3.10.2013
Acute Tox. 3 H311 H311
STOT RE 1 H372
(blood) H372
(blood)
Aquatic Chronic 3 H412 H412

---

3.10.2013 Off
Classification Labelling
Index No International
Chemical
Identification EC
No CAS
No
Suppl.
Specific Conc. Limits,
Hazard statement
Pictogram,
Hazard statement
Hazard
M — Factors
Notes
Hazard Class and
Category Code(s)
Code(s)
Signal Word
Code(s)
Code(s)
statement
Code(s)
612-120-00-6 aclonifen
(ISO);
277-704-1 74070-46-5 Carc.
2 H351 GHS08 H351 M
=
100
EN
2-chloro-6-nitro-3-phenoxyaniline
M = 10
Skin Sens. 1A H317 GHS07 H317

Aquatic Acute 1 H400 GHS09
Aquatic Chronic 1 H410 Wng H410
613-175-00-9 epoxiconazole
(ISO);
406-850-2 133855-98-8 Carc.
2 H351 GHS08 H351
(2RS,3SR)-3-(2-chlorophenyl)-2-(4-
Repr. 1B H360Df GHS09 H360Df
fluorophenyl)-[( 1H-1,2,4-triazol-1-
yl)methyl]oxirane
Aquatic Chronic 2 H411 Dgr H411
icial
616-200-00-1 reaction
mass
of
N,N’-ethane-1,2-
432-430-3 Aquatic
Chronic
4 H413 H413
diylbis(hexanamide) and 12-hydroxy-N-
Jour
[2-[(1-oxyhexyl)amino]ethyl]octadec
nal
anamide and N,N’-ethane-1,2-
diylbis(12-hydroxyoctadecan amide)
of
the
European
648-055-00-5 pitch,
coal
tar,
high-temp.;
266-028-2 65996-93-2 Carc.
1A H350 GHS08 H350 M
=
1000
[The residue from the distillation of
M = 1000
Muta. 1B H340 GHS09 H340
high temperature coal tar. A black solid
with an approximate softening point
Repr. 1B H360FD Dgr H360FD
Union
from 30 °C to 180 °C (86 °F to 356 °F).
Aquatic Acute 1 H400
Composed primarily of a complex
Aquatic Chronic 1 H410 H410
mixture of three or more membered
condensed ring aromatic hydrocar
bons.]
649-330-00-2 naphtha
(petroleum),
hydrodesul
265-185-4 64742-82-1 Carc.
1B H350 GHS08 H350
P
phurized heavy;
Muta. 1B H340 Dgr H340
Low boiling point hydrogen treated
naphtha;
STOT RE 1 H372
(central
H372 (central
[A complex combination of hydro
nervous
nervous
carbons obtained from a catalytic
system)
system)
hydrodesulfurization process. It consists
Asp. Tox. 1 H304 H304
of hydrocarbons having carbon
numbers predominantly in the range of
C7 through C12 and boiling in the
L
range of approximately 90 °C to
261/11
230 °C (194 °F to 446 °F).]

---

L 261/12
Classification Labelling
Index No International
Chemical
Identification EC
No CAS
No
Suppl.
Specific Conc. Limits,
Hazard statement
Pictogram,
Hazard statement
Hazard
M — Factors
Notes
Hazard Class and
Category Code(s)
Code(s)
Signal Word
Code(s)
Code(s)
statement
Code(s)
649-345-00-4 stoddard
solvent;
232-489-3 8052-41-3 Carc.
1B H350 GHS08 H350
P
EN
Low boiling point naphtha —

unspecified;
Muta. 1B H340 Dgr H340
[A colourless, refined petroleum
STOT RE 1 H372
(central
H372 (central
distillate that is free from rancid or
nervous
nervous
objectionable odours and that boils in a
system)
system)
range of approximately 148,8 °C to
Asp. Tox. 1 H304 H304
204,4 °C (300 °F to 400 °F).]
649-405-00-X solvent
naphtha
(petroleum),
medium 265-191-7 64742-88-7 STOT
RE
1 H372
(central
GHS08 H372
(central
aliph.;
nervous
nervous
Off
Straight run kerosine;
system)
system)
icial
[A complex combination of hydro
Asp. Tox. 1 H304 Dgr H304
carbons obtained from the distillation
Jour
of crude oil or natural gasoline. It
consists predominantly of saturated
nal
hydrocarbons having carbon numbers
of
predominantly in the range of C9
the
through C12 and boiling in the range
of approximately 140 °C to 220 °C
European
(284 °F to 428 °F).]
Union
3.10.2013

---

3.10.2013 Off
ANNEX III
Classification Labelling
Specific Conc.
Index No International
Chemical
Identification EC
No CAS
No
Pictogram,
Suppl.
Limits,
Notes
Hazard Class and
Signal Word Hazard statement Code(s)
Hazard
M — Factors
Category Code(s)
Hazard statement Code(s)
Code(s)
statement
EN
Code(s)

031-001-00-4 gallium
arsenide 215-114-8 1303-00-0 Carc.
1B H350 GHS08 H350
STOT RE 1 H372
(respiratory
Dgr H372
(respiratory
and haematopoietic
and haematopoietic
systems)
systems)
050-025-00-6 trichloromethylstannane 213-608-8 993-16-8 Repr.
2 H361d GHS08
H361d
Wng
050-026-00-1 2-ethylhexyl
10-ethyl-4-[[2-[(2- 260-828-5 57583-34-3 Repr.
2 H361d GHS08
H361d
icial
ethylhexyl)oxy]-2-oxoethyl]thio]-
Wng
4-methyl-7-oxo-8-oxa-3,5-dithia-
Jour
4-stannatetradecanoate
nal
of
050-027-00-7 2-ethylhexyl
10-ethyl-4,4-
239-622-4 15571-58-1 Repr.
1B H360D GHS08
H360D
the
dioctyl-7-oxo-8-oxa-3,5-dithia-4-
Dgr
stannatetradecanoate
European
601-087-00-3 2,4,4-trimethylpentene 246-690-9 25167-70-8 Flam.
Liq.
2 H225 GHS02 H225
D
Asp. Tox. 1 H304 GHS07 H304
Union
STOT SE 3 H336 GHS08
H336
Dgr
606-145-00-1 sulcotrione
(ISO);
99105-77-8 Repr.
2 H361d GHS08 H361d M
=
1
2-[2-chloro-4-(methylsulfo
STOT RE 2 H373
(kidneys) GHS07 H373
(kidneys)
M = 10
nyl)benzoyl]cyclohexane-1,3-
Skin Sens. 1A H317 GHS09 H317
dione
Aquatic Acute 1 H400 Wng
Aquatic Chronic 1 H410 H410
607-699-00-7 bifenthrin
(ISO);
82657-04-3 Carc.
2 H351 GHS06 H351 M
=
10
000
(2-methylbiphenyl-3-yl)methyl
Acute Tox. 3 H331 GHS08 H331
M = 100 000
rel-(1R,3R)-3-[(1Z)-2-chloro-
Acute Tox. 2 H300 GHS09 H300
3,3,3-trifluoroprop-1-en-1-yl]-
2,2-dimethylcyclopropanecar
STOT RE 1 H372
(nervous Dgr H372
(nervous
boxylate
system)
system)
Skin Sens. 1B H317 H317
L
261/13
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410

---

L 261/14
Classification Labelling
Specific Conc.
Index No International
Chemical
Identification EC
No CAS
No
Pictogram,
Suppl.
Limits,
Notes
Hazard Class and
Signal Word Hazard statement Code(s)
Hazard
M — Factors
Category Code(s)
Hazard statement Code(s)
Code(s)
statement
Code(s)
607-700-00-0 indoxacarb
(ISO);
173584-44-6 [1] Acute
Tox.
3 H301 GHS06 H301 M
=
1
EN
methyl (4aS)-7-chloro-2-{(me
Acute Tox. 4 H332 GHS08 H332
M = 1

thoxycarbonyl)[4-(trifluorome
STOT RE 1 H372
(blood,
nervous
GHS09 H372
(blood,
nervous
thoxy)phenyl]carbamoyl}-2,5-
system, heart)
system, heart)
dihydroindeno[1,2-e][1,3,4]ox
Skin Sens. 1B H317 Dgr H317
adiazine-4a(3H)-carboxylate [1]
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410
reaction mass of (S)- Indoxacarb
144171-61-9 [2]
and (R)- Indoxacarb 75:25;
methyl 7-chloro-2-{(methoxycar
bonyl)[4-(trifluoromethoxy)phe
Off
nyl]carbamoyl}-2,5-dihydro
icial
indeno[1,2-e][1,3,4]oxadiazine-
4a(3H)-carboxylate [2]
Jour
nal
607-702-00-1 dihexyl
phthalate 201-559-5 84-75-3 Repr.
1B H360FD GHS08
H360FD
Dgr
of
the
607-703-00-7 ammoniumpentadeca-
223-320-4 3825-26-1 Carc.
2 H351 GHS08 H351
European
fluorooctanoate
Repr. 1B H360D GHS07 H360D
Lact. H362 GHS05 H362
Acute Tox. 4 H332 Dgr H332
Union
Acute Tox. 4 H302 H302
STOT RE 1 H372
(liver) H372
(liver)
Eye Dam.1 H318 H318
607-704-00-2 perfluorooctanoic
acid 206-397-9 335-67-1 Carc.
2 H351 GHS08 H351
Repr. 1B H360D GHS07 H360D
Lact. H362 GHS05 H362
Acute Tox. 4 H332 Dgr H332
Acute Tox. 4 H302 H302
STOT RE 1 H372
(liver) H372
(liver)
Eye Dam. 1 H318 H318
612-282-00-8 octadecylamine 204-695-3 124-30-1 Asp.
Tox.
1 H304 GHS05 H304 M
=
10
STOT RE 2 H373
GHS08 H373
M = 10
(gastro-intestinal tract,
(gastro-intestinal tract,
liver, immune system)
liver, immune system)
Skin Irrit. 2 H315 GHS09 H315
3.10.2013
Eye Dam. 1 H318 Dgr H318
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410

---

3.10.2013 Off
Classification Labelling
Specific Conc.
Index No International
Chemical
Identification EC
No CAS
No
Pictogram,
Suppl.
Limits,
Notes
Hazard Class and
Signal Word Hazard statement Code(s)
Hazard
M — Factors
Category Code(s)
Hazard statement Code(s)
Code(s)
statement
Code(s)
612-283-00-3 (Z)-octadec-9-enylamine 204-015-5 112-90-3 Acute
Tox.
4 H302 GHS05 H302 M
=
10
EN
M = 10
Asp Tox. 1 H304 GHS07 H304

STOT SE 3 H335 GHS08 H335
STOT RE 2 H373
GHS09 H373
(gastro-intestinal tract,
(gastro-intestinal tract,
liver, immune system)
liver, immune system)
Skin Corr. 1B H314 Dgr H314
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410
612-284-00-9 amines,
hydrogenated
tallow
262-976-6 61788-45-2 Asp
Tox.
1 H304 GHS08 H304 M
=
10
icial
alkyl
M = 10
STOT RE 2 H373
GHS05 H373
(gastro-intestinal tract,
(gastro-intestinal tract,
Jour
liver, immune system)
liver, immune system)
nal
Skin Irrit. 2 H315 GHS09 H315
of
Eye Dam. 1 H318 Dgr H318
the
Aquatic Acute 1 H400
European
Aquatic Chronic 1 H410 H410
612-285-00-4 amines,
coco
alkyl 262-977-1 61788-46-3 Acute
Tox.
4 H302 GHS05 H302 M
=
10
Union
M = 10
Asp. Tox. 1 H304 GHS07 H304
STOT SE 3 H335 GHS08 H335
STOT RE 2 H373
GHS09 H373
(gastro-intestinal tract,
(gastro-intestinal tract,
liver, immune system)
liver, immune system)
Skin Corr. 1B H314 Dgr H314
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410
612-286-00-X amines,
tallow
alkyl 263-125-1 61790-33-8 Acute
Tox.
4 H302 GHS05 H302 M
=
10
M = 10
Asp. Tox. 1 H304 GHS07 H304
STOT RE 2 H373
GHS08 H373
(gastro-intestinal tract,
(gastro-intestinal tract,
liver, immune system)
liver, immune system)
Skin Corr. 1B H314 GHS09 H314
L
Aquatic Acute 1 H400 Dgr
261/15
Aquatic Chronic 1 H410 H410

---

L 261/16
Classification Labelling
Specific Conc.
Index No International
Chemical
Identification EC
No CAS
No
Pictogram,
Suppl.
Limits,
Notes
Hazard Class and
Signal Word Hazard statement Code(s)
Hazard
M — Factors
Category Code(s)
Hazard statement Code(s)
Code(s)
statement
Code(s)
616-206-00-4 flufenoxuron
(ISO);
417-680-3 101463-69-8 Lact. H362 GHS09 H362 M
=
10
000
EN
1-(4-(2-cloro-α,α,α-p-trifluor
Aquatic Acute 1 H400 Wng
M = 10 000

otolyloxy)-2-fluorophenyl)-3-
Aquatic Chronic 1 H410 H410
(2,6-difluorobenzolyl)urea
616-207-00-X polyhexamethylene
biguanide
27083-27-8 or
Carc. 2 H351 GHS05 H351 M
=
10
hydrochloride
32289-58-0
Acute Tox. 4 H302 GHS07 H302
M = 10
STOT RE 1 H372
(respiratory
GHS08 H372
(respiratory
tract) (inhalation)
tract) (inhalation)
Eye Dam. 1 H318 GHS09 H318
Skin Sens. 1B H317 Dgr H317
Aquatic Acute 1 H400
Off
Aquatic Chronic 1 H410 H410
icial
Jour
616-208-00-5 N-ethyl-2-pyrrolidone;
220-250-6 2687-91-4 Repr.
1B H360D GHS08
H360D
1-ethylpyrrolidin-2-one
Dgr
nal
of
616-209-00-0 amidosulfuron
(ISO);
407-380-0 120923-37-7 Aquatic
Acute
1 H400 GHS09 M
=
100
the
3-(4,6-dimethoxypyrimidin-2-yl)-
Aquatic Chronic 1 H410 Wng H410
M = 100
1-((N-methyl-N-methylsulfony
European
lamino)sulfonyl)urea
616-210-00-6 tebufenpyrad
(ISO);
119168-77-3 Acute
Tox.
3 H301 GHS06 H301 M
=
10
Union
N-(4-tertbutylbenzyl)-4-chloro-3-
Acute Tox. 4 H332 GHS08 H332
M = 10
ethyl-1-methyl-1Hpyrazole-5-
STOT RE 2 H373
GHS09 H373
carboxamide
(gastro-intestinal
(gastro-intestinal
tract) (Oral)
tract) (Oral)
Skin Sens. 1B H317 Dgr H317
Aquatic Acute 1 H400
Aquatic Chronic 1 H410 H410
616-211-00-1 proquinazid
(ISO);
189278-12-4 Carc.
2 H351 GHS08 H351 M
=
1
6-iodo-2-propoxy-3-propylqui
Aquatic Acute 1 H400 GHS09
M = 10
nazolin-4(3H)-one
Aquatic Chronic 1 H410 Wng H410
3.10.2013

---

3.10.2013 Off
ANNEX IV
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
015-004-00-8 aluminium
phosphide 244-088-0 20859-73-8 F;
R15/29
F; T+; N
N; R50: C ≥ 0,25 %
T+; R26/28
R: 15/29-21-26/28-32-50
EN
Xn; R21
S: (1/2-)3/9/14/49-8-22-30-

R32
36/37-43-45-60-61
N; R50
015-005-00-3 magnesium
phosphide;
235-023-7 12057-74-8 F;
R15/29
F; T+; N
N; R50: C ≥ 0,25 %
trimagnesium diphosphide
T+; R26/28
R: 15/29-21-26/28-32-50
Xn; R21
S: (1/2-)3/9/14/49-8-22-30-
R32
36/37-43-45-60-61
N; R50
015-123-00-5 fenamiphos
(ISO);
244-848-1 22224-92-6 T+;
R26/28
T+; N
N; R50-53: C ≥ 0,25 %
icial
ethyl-4-methylthio-m-tolyl isopropyl phos
T; R24
R: 24-26/28-36-50/53
N; R51-53: 0,025 % ≤ C <
phoramidate
Xi; R36
S: (1/2-)23-26-28-35-36/37- 0,25 %
Jour
N; R50-53
45-60-61
R52-53: 0,0025 % ≤ C <
nal
0,025 %
of
the
030-012-00-1 aluminium-magnesium-zinc-carbonate- 423-570-6 169314-88-9 R53 R:
53
European
hydroxide
S: 61
602-006-00-4 chloroform;
200-663-8 67-66-3 Carc.
Cat.
3;
R40
Xn
Union
trichloromethane
Repr. Cat. 3; R63
R: 20/22-36/38-40-48/20-
Xn; R20/22-48/20
63
Xi; R36/38
S: (2-)36/37
603-097-00-3 1,1′,1′′-nitrilotripropan-2-ol;
204-528-4 122-20-3 Xi;
R36 Xi
triisopropanolamine
R: 36
S: (2-)26
605-008-00-3 acrolein;
203-453-4 107-02-8 F;
R11
F; T+; N
C; R34: C ≥ 0,1 %
D
prop-2-enal;
T+; R26/28
R: 11-24-26/28-34-50
N; R50: C ≥ 0,25 %
acrylaldehyde
T; R24
S: (1/2-)23-26-28-36/37/39-
C; R34
45-61
N; R50
607-023-00-0 vinyl
acetate 203-545-4 108-05-4 F;
R11
F; Xn
D
L
Carc. Cat. 3; R40
R: 11-20-37-40
261/17
Xn; R20
S: 9-16-33-36/37
Xi; R37

---

L 261/18
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
607-613-00-8 reaction
mass
of:
432-790-1 C;
R34
C
succinic acid
Xn; R20/21/22-68/20/21/22 R: 20/21/22-34-
monopersuccinic acid
68/20/21/22
dipersuccinic acid
S: (1/2-)26-28-36/37/39-45
monomethyl ester of succinic acid
monomethyl ester of persuccinic acid
EN
dimethyl succinate

glutaric acid
monoperglutaric acid
diperglutaric acid
monomethyl ester of glutaric acid
monomethyl ester of perglutaric acid
dimethyl glutarate
adipic acid
monoperadipic acid
diperadipic acid
monomethyl ester of adipic acid
Off
monomethyl ester of peradipic acid
icial
dimethyl adipate
hydrogen peroxide
Jour
methanol
nal
water
of
the
609-003-00-7 nitrobenzene 202-716-0 98-95-3 Carc.
Cat.
3;
R40
T
European
Repr. Cat. 2; R60
R: 23/24/25-48/23/24/25-
T; R23/24/25-48/23/24/25
40-60-52/53
R52-53
S: 45-53
Union
612-120-00-6 aclonifen
(ISO);
277-704-1 74070-46-5 Carc.
Cat.
3;
R40
Xn; N
R43: C ≥ 0,1 %
2-chloro-6-nitro-3-phenoxyaniline
R43
R: 40-43-50/53
N; R50-53: C ≥ 0,25 %
N; R50-53
S: (2-)36/37-60-61
N; R51-53: 0,025 % ≤ C <
0,25 %
R52-53: 0,0025 % ≤ C <
0,025 %
613-175-00-9 epoxiconazole
(ISO);
406-850-2 133855-98-8 Carc.
Cat.
3;
R40
T; N
(2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluor
Repr. Cat. 2; R61
R: 61-40-62-51/53
ophenyl)-[(1H-1,2,4-triazol-1-yl)methyl]ox
Repr. Cat. 3; R62
S: 45-53-61
irane
N; R51-53
616-200-00-1 reaction
mass
of
N,N’-ethane-1,2-
432-430-3 R53 R:
53
diylbis(hexanamide) and 12-hydroxy-N-[2-
S: 61
3.10.2013
[(1-oxyhexyl)amino]ethyl]octadecanamide
and N,N’-ethane-1,2-diylbis(12-hydroxyoc
tadecan amide)

---

3.10.2013 Off
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
648-055-00-5 pitch,
coal
tar,
high-temp.;
266-028-2 65996-93-2 Carc.
Cat.
1;
R45
T; N
N; R50-53: C ≥ 0,025 %
[The residue from the distillation of high
Muta. Cat. 2; R46
R: 45-46-60-61-50/53
N; R51-53: 0,0025 % ≤ C <
temperature coal tar. A black solid with an
Repr. Cat. 2; R60-61
S: 45-53-60-61
0,025 %
approximate softening point from 30 °C to
N; R50-53
R52-53: 0,00025 % ≤ C <
180 °C (86 °F to 356 °F). Composed
0,0025 %
primarily of a complex mixture of three or
EN
more membered condensed ring aromatic

hydrocarbons.]
649-330-00-2 naphtha
(petroleum),
hydrodesulphurized
265-185-4 64742-82-1 Carc.
Cat.
2;
R45
T
P
heavy;
Muta. Cat. 2; R46
R: 45-46-48/20-65
Low boiling point hydrogen treated naphtha;
Xn; R48/20-65
S: 45-53
[A complex combination of hydrocarbons
obtained from a catalytic hydrodesulfur
ization process. It consists of hydrocarbons
having carbon numbers predominantly in
the range of C7 through C12 and boiling
icial
in the range of approximately 90 °C to
230 °C (194 °F to 446 °F).]
Jour
nal
649-345-00-4 stoddard
solvent;
232-489-3 8052-41-3 Carc.
Cat.
2;
R45
T
P
Low boiling point naphtha — unspecified;
Muta. Cat. 2; R46
R: 45-46-48/20-65
of
[A colourless, refined petroleum distillate
Xn; R48/20-65
S: 45-53
the
that is free from rancid or objectionable
European
odours and that boils in a range of approxi
mately 148,8 °C to 204,4 °C (300 °F to 400
°F).]
Union
649-405-00-X solvent
naphtha
(petroleum),
medium
aliph.;
265-191-7 64742-88-7 Xn;
R48/20-65 Xn
Straight run kerosine;
R: 48/20-65
[A complex combination of hydrocarbons
S: (2-)23-24-62
obtained from the distillation of crude oil
or natural gasoline. It consists predomi
nantly of saturated hydrocarbons having
carbon numbers predominantly in the
range of C9 through C12 and boiling in
the range of approximately 140
°C to
220 °C (284 °F to 428 °F).]
L
261/19

---

L 261/20
ANNEX V
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
031-001-00-4 gallium
arsenide 215-114-8 1303-00-0 Carc.
Cat.
2;
R45 T
E
T; R48/23
R: 45-48/23
EN
S: 45-53

050-025-00-6 trichloromethylstannane 213-608-8 993-16-8 Repr.
Cat.
3;
R63 Xn
R: 63
S: (2-)22-36/37
050-026-00-1 2-ethylhexyl
10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2- 260-828-5 57583-34-3 Repr.
Cat.
3;
R63 Xn
oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-
R: 63
stannatetradecanoate
S: (2-)22-36/37
Off
050-027-00-7 2-ethylhexyl
10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5- 239-622-4 15571-58-1 Repr.
Cat.
2;
R61 T
icial
dithia-4-stannatetradecanoate
R: 61
Jour
S: 45-53
nal
601-087-00-3 2,4,4-trimethylpentene 246-690-9 25167-70-8 F;
R11
F; Xn
D
of
Xn; R65
R: 11-65-67
the
R67
S: 9-16-33-62
European
606-145-00-1 sulcotrione
(ISO);
99105-77-8 Repr.
Cat.
3;
R63 Xn; N
N; R50-53: C ≥ 25 %
2-[2-chloro-4-(methylsulfonyl)benzoyl]cyclohexane-
Xn; R48/22
R: 43-48/22-63-50/53
N; R51-53: 2,5 % ≤ C < 25 %
1,3-dione
R43
S: (2-)22-36/37-60-61
R52-53: 0,25 % ≤ C< 2,5 %
Union
N; R50-53
R43: C ≥ 0,1 %
607-699-00-7 bifenthrin
(ISO);
82657-04-3 Carc.
Cat
3;
R40 T; N
N; R50-53: C ≥ 0,0025 %
(2-methylbiphenyl-3-yl)methyl rel-(1R,3R)-3-[(1Z)-2-
T; R23/25
R: 23/25-40-43-48/22-
N; R51-53: 0,00025 % ≤ C<
chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethyl
Xn; R48/22
50/53
0,0025 %
cyclopropanecarboxylate
R43
S: (1/2-)23-24-36/37-38-
R52-53: 0,000025 % ≤ C <
N; R50-53
45-60-61
0,00025 %
607-700-00-0 indoxacarb
(ISO);
173584-44-6 T;
R25-48/25
T; N
N; R50-53: C ≥ 25 %
methyl (4aS)-7-chloro-2-{(methoxycarbonyl)[4-(tri
Xn; R20
R: 20-25-43-48/25-50/53
N; R51-53: 2,5 % ≤ C < 25 %
fluoromethoxy)phenyl]carbamoyl}-2,5-dihydro
R43
S: (1/2-)24-37-45-60-61
R52-53: 0,25 % ≤ C < 2,5 %
indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate
N; R50-53
607-701-00-6 reaction
mass
of
(S)-
Indoxacarb
and
(R)-
Indoxacarb
144171-61-9 T;
R48/25
T; N
N; R50-53: C ≥ 25 %
75:25;
Xn; R20/22
R: 20/22-43-48/25-50/53
N; R51-53: 2,5 % ≤ C < 25 %
3.10.2013
methyl 7-chloro-2-{(methoxycarbonyl)[4-(trifluor
R43
S: (1/2-)24-37-45-60-61
R52-53: 0,25 % ≤ C < 2,5 %
omethoxy)phenyl]carbamoyl}-2,5-dihydro
N; R50-53
indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate

---

3.10.2013 Off
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
607-702-00-1 dihexyl
phthalate 201-559-5 84-75-3 Repr.
Cat.
2;
R60-61 T
R: 60-61
S: 45-53
607-703-00-7 ammoniumpentade-cafluorooctanoate 223-320-4 3825-26-1 Carc.
Cat.
3;
R40 T
EN
Repr. Cat. 2; R61
R: 61-20/22-40-41- 48/23-

R64
48/21/22-64
T; R48/23
S: 45-53
Xn; R20/22-48/21/22
Xi; R41
607-704-00-2 perfluorooctanoic
acid 206-397-9 335-67-1 Carc.
Cat.
3;
R40
T
Repr. Cat. 2; R61
R: 61-20/22-40-41-48/23-
R64
48/21/22-64
T; R48/23
S: 45-53
Xn; R20/22-48/21/22
Xi; R41
icial
Jour
612-282-00-8 octadecylamine 204-695-3 124-30-1 Xn;
R48/22-65 Xn; N
N; R50-53: C ≥ 2,5 %
Xi; R38-41
R: 38-41-48/22-65-50/53
N; R51-53: 0,25 % ≤ C <
nal
N; R50-53
S: (2-)26-36/37/39-60-61-
2,5 %
of
62
R52-53: 0,025 % ≤ C <
the
0,25 %
European
612-283-00-3 (Z)-octadec-9-enylamine 204-015-5 112-90-3 Xn;
R22-48/22-65
C; N
C; R34: C ≥ 10 %
C; R34
R: 22-34-48/22-65-50/53
Xi; R36/37/38: 5 % ≤ C <
N; R50-53
S: (1/2-)23-26-36/37/39-45- 10 %
Union
60-61-62
N; R50-53: C ≥ 2,5 %
N; R51-53: 0,25 % ≤ C <
2,5 %
R52-53: 0,025 % ≤ C <
0,25 %
612-284-00-9 amines,
hydrogenated
tallow
alkyl 262-976-6 61788-45-2 Xn;
R48/22-65
Xn; N
N; R50-53: C ≥ 2,5 %
Xi; R38-41
R: 38-41-48/22-65-50/53
N; R51-53: 0,25 % ≤ C <
N; R50-53
S: (2-)26-36/37/39-60-61-
2,5 %
62
R52-53: 0,025 % ≤ C <
0,25 %
612-285-00-4 amines,
coco
alkyl 262-977-1 61788-46-3 Xn;
R22-48/22-65 C; N
C; R35: C ≥ 10 %
C; R35
R: 22-35-48/22-65-50/53
C; R34: 5 % ≤ C < 10 %
N; R50-53
S: (1/2-)23-26-36/37/39-45- Xi; R36/37/38: 1 % ≤ C < 5 %
60-61-62
N; R50-53: C ≥ 2,5 %
N; R51-53: 0,25 % ≤ C <
L
2,5 %
261/21
R52-53: 0,025 % ≤ C <
0,25 %

---

L 261/22
Index No International
Chemical
Identification EC
No CAS
No Classification Labelling Concentration
Limits Notes
612-286-00-X amines,
tallow
alkyl 263-125-1 61790-33-8 Xn;
R22-48/22-65 C; N
N; R50-53: C ≥ 2,5 %
C; R35
R: 22-35-48/22-65-50/53
N; R51-53: 0,25 % ≤ C <
N; 50-53
S: (1/2-)26-36/37/39-45-60- 2,5 %
61-62
R52-53: 0,025 % ≤ C <
0,25 %
EN

616-206-00-4 flufenoxuron
(ISO);
417-680-3 101463-69-8 R64
N
N; R50-53 C ≥ 0,0025 %
1-(4-(2-cloro-α,α,α-p-trifluorotolyloxy)-2-fluor
R33
R: 33-64-50/53
N; R51-53 0,00025 % ≤ C <
ophenyl)-3-(2,6-difluorobenzolyl)urea
N; R50-53
S: (2-)22-36/37-46-60-61
0,0025 %
R52-53 0,000025 % ≤ C <
0,00025 %
616-207-00-X polyhexamethylene
biguanide
hydrochloride 27083-27-8
or
Carc. Cat 3; R40
T; N
N; R50-53: C ≥ 2,5 %
32289-58-0
Xn; R22
R: 22-40-41-43-48/23-
N; R51-53: 0,25 % ≤ C <
T; R48/23
50/53
2,5 %
Xi; R41
S: (1/2-)22-36/37/39-45-60- R52-53: 0,025 % ≤ C <
Off
R43
61
0,25 %
icial
N; R50-53
Jour
616-208-00-5 N-ethyl-2-pyrrolidone;
220-250-6 2687-91-4 Repr.
Cat.
2;
R61 T
nal
1-ethylpyrrolidin-2-one
R: 61
of
S: 45-53
the
European
616-209-00-0 amidosulfuron
(ISO);
407-380-0 120923-37-7 N;
R50-53 N
N; R50-53: C ≥ 0,25 %
3-(4,6-dimethoxypyrimidin-2-yl)-1-((N-methyl-N-
R: 50/53
N; R51-53: 0,025 % ≤ C <
methylsulfonylamino)sulfonyl)urea
S: 60-61
0,25 %
R52-53: 0,0025 % ≤ C <
Union
0,025 %
616-210-00-6 tebufenpyrad
(ISO);
119168-77-3 Xn;
R20/22
Xn; N
N; R50-53: C ≥ 2,5 %
N-(4-tertbutylbenzyl)-4-chloro-3-ethyl-1-methyl-
R43
R: 20/22-43-50/53
N; R51-53: 0,25 % ≤ C <
1Hpyrazole-5-carboxamide
N; R50-53
S: (2-)24-37-46-60-61
2,5 %
R52-53: 0,025 % ≤ C <
0,25 %
616-211-00-1 proquinazid
(ISO);
189278-12-4 Carc.
Cat.
3;
R40 Xn; N
6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one
N; R50-53
R: 40-50/53
S: (2-)36/37-46-60-61
3.10.2013

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Document Outline

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